There are a couple ways to solve this but I really recommend to use bootstrap itself to do it.
What I recommend is using offsets. So if you want your form centered just use something like:
<div class="form-group row" id="SignupCreate">
<div class="col-sm-4 col-sm-offset-4">
<label>Email</label>
<input type="email" class="form-control" id="inputEmail" placeholder="Email">
</div>
<div class="col-sm-4 col-sm-offset-4">
<label>Password</label>
<input type="password" class="form-control" id="inputPassword" placeholder="Password">
<div class="col-sm-4">
<button type="submit">Submit</button>
</div>
</div>
</div>
You can tweak your offsets for xs, sm, md and lg accordingly, make sure to set offset to 0 if you don't want offset in a particular view.
Now for your styles, you are giving css a SignUpCreate id when in fact is SignupCreate, remember css selectors are case sensitive.
Also keep in mind for the future that when using bootstrap you should try as much to stick to the framework and use all its features instead of coding your own CSS, and when you do, a good thing to keep in mind is that CSS uses "points" to know which styles are more relevant, I recommend checking Specifics on CSS Specificity
So let's say you want to style something that has padding right and left, I would avoid using a row or column element to do this and would add a second container div to "respect" bootstrap styles.
I hope this answer is helpful :)
There is also a good answer here: Center a column using Twitter Bootstrap 3
UPDATE:
With boostrap 4.5^ you can center any item using d-flex justify-content-center
on the parent, if you also want to align the items vertically (relative to the parent's height) simply add align-items-center
.