How to select unique results from both columns:
+---------+--------------+
| team_id | opponents_id |
+---------+--------------+
| 1 | 2 |
| 1 | 3 |
| 1 | 4 |
| 1 | 5 |
| 1 | 6 |
| 2 | 1 |
| 2 | 3 |
| 2 | 4 |
| 2 | 5 |
| 2 | 6 |
| 3 | 1 |
| 3 | 2 |
| 3 | 4 |
| 3 | 5 |
| 3 | 6 |
| 4 | 1 |
| 4 | 2 |
| 4 | 3 |
| 4 | 5 |
| 4 | 6 |
| 5 | 1 |
| 5 | 2 |
| 5 | 3 |
| 5 | 4 |
| 5 | 6 |
| 6 | 1 |
| 6 | 2 |
| 6 | 3 |
| 6 | 4 |
| 6 | 5 |
+---------+--------------+