The word model is used in, at least, two senses. There is your domain model. Here the sense is how you represent your data. There are many ways to structure your data and also many ways to access it. When we talk about the model in this sense we're not particularly concerned with how you are accessing the structures that make it up, i.e., the data access or persistence layer, although you may also hear people speak of the model of persistence. By this, people mean the particular philosophy that the persistence implementation uses, such as ActiveRecord or Repository. You might also hear these referred to as patterns.
Finally, the word model has a very specific meaning in MVC, MVP, and MVVM in the context of a view. In that context it means that particular data object associated with a view, the view model. This could be one of your domain objects, but more typically it is a view-specific object that encapsulates data from one or more domain objects along with ancillary data such as user data that is used by a particular view.
For your application, choose the persistence model that best suits your development environment and language -- LINQ to SQL, LINQ to Entities, nHibernate, Castle ActiveRecord, etc. in the MS world Create view-specific models (classes) for each of your views that hold the data needed by that view. Use your controllers to query your domain model to extract the information needed by the view and map that onto the view model.