As Barry Wark said, remember always that Core Data is not an orm. Pure SQL details are not exposed to the user and every row is just an object. By the way, sometime you should need to access the "primary key", for example when you need to sync the coredata db with external sql databases (in my case I needed it in a callback function to change the state of an object after INSERT it with success in the remote db). In this case, you can use:
objectId = [[[myCoredataObject objectID] URIRepresentation] absoluteString]
that will return a string like: x-coredata://76BA122F-0BF5-4D9D-AE3F-BD321271B004/Object/p521
that is the unique id used by Core Data to identify that object.
If you want to get back an object with that unique id:
NSManagedObject *managedObject = [managedObjectContext objectWithID:[persistentStoreCoordinator managedObjectIDForURIRepresentation:[NSURL URLWithString:objectId]]];
NB: Remember that if the receiver has not yet been saved in the CoreData Context, the object ID is a temporary value that will change when the object is saved.