The class Collator is part of the intl extension, so if you don't have it or you can't install it, I suggest you to use this utility conversion array in this answer Replacing accented characters php
<?php
$unwanted_array = array('Š'=>'S', 'š'=>'s', 'Ž'=>'Z', 'ž'=>'z', 'À'=>'A', 'Á'=>'A', 'Â'=>'A', 'Ã'=>'A', 'Ä'=>'A', 'Å'=>'A', 'Æ'=>'A', 'Ç'=>'C', 'È'=>'E', 'É'=>'E',
'Ê'=>'E', 'Ë'=>'E', 'Ì'=>'I', 'Í'=>'I', 'Î'=>'I', 'Ï'=>'I', 'Ñ'=>'N', 'Ò'=>'O', 'Ó'=>'O', 'Ô'=>'O', 'Õ'=>'O', 'Ö'=>'O', 'Ø'=>'O', 'Ù'=>'U',
'Ú'=>'U', 'Û'=>'U', 'Ü'=>'U', 'Ý'=>'Y', 'Þ'=>'B', 'ß'=>'Ss', 'à'=>'a', 'á'=>'a', 'â'=>'a', 'ã'=>'a', 'ä'=>'a', 'å'=>'a', 'æ'=>'a', 'ç'=>'c',
'è'=>'e', 'é'=>'e', 'ê'=>'e', 'ë'=>'e', 'ì'=>'i', 'í'=>'i', 'î'=>'i', 'ï'=>'i', 'ð'=>'o', 'ñ'=>'n', 'ò'=>'o', 'ó'=>'o', 'ô'=>'o', 'õ'=>'o',
'ö'=>'o', 'ø'=>'o', 'ù'=>'u', 'ú'=>'u', 'û'=>'u', 'ý'=>'y', 'þ'=>'b', 'ÿ'=>'y' );
$previous = null;
foreach($rows as $row1) {
$firstLetter = substr($row1->titolo, 0, 1);
$firstLetter = strtr( $firstLetter, $unwanted_array );
if($previous !== $firstLetter) echo $firstLetter."<br />";
$previous = $firstLetter;
echo $row1->titolo;
}
?>