With new versions of openssl, configurations goes in exclusion-way. You can use this command to test SSLv3 protocol
openssl s_client -connect youserver:443 -no_tls1_2 -no_tls1_1 -no_tls1
But the best way to ensure wich versions of SSL/TLS are working on the remote werver is using NMAP:
nmap -sV --script ssl-enum-ciphers -p 443 youserver
Nmap output will point you in the right direction, because it describes the version working protocols and every available cipher.
PORT STATE SERVICE VERSION
443/tcp open ssl/https nginx
|_http-server-header: nginx
| ssl-enum-ciphers:
| TLSv1.0:
| ciphers:
| TLS_DHE_RSA_WITH_AES_128_CBC_SHA (dh 1024) - A
| TLS_DHE_RSA_WITH_AES_256_CBC_SHA (dh 1024) - A
| TLS_ECDHE_RSA_WITH_AES_128_CBC_SHA (secp256r1) - A
| TLS_ECDHE_RSA_WITH_AES_256_CBC_SHA (secp256r1) - A
| compressors:
| NULL
| cipher preference: client
| warnings:
| Key exchange (dh 1024) of lower strength than certificate key
| TLSv1.1:
| ciphers:
| TLS_DHE_RSA_WITH_AES_128_CBC_SHA (dh 1024) - A
| TLS_DHE_RSA_WITH_AES_256_CBC_SHA (dh 1024) - A
| TLS_ECDHE_RSA_WITH_AES_128_CBC_SHA (secp256r1) - A
| TLS_ECDHE_RSA_WITH_AES_256_CBC_SHA (secp256r1) - A
| compressors:
| NULL
| cipher preference: client
| warnings:
| Key exchange (dh 1024) of lower strength than certificate key
| TLSv1.2:
| ciphers:
| TLS_DHE_RSA_WITH_AES_128_CBC_SHA (dh 1024) - A
| TLS_DHE_RSA_WITH_AES_128_CBC_SHA256 (dh 1024) - A
| TLS_DHE_RSA_WITH_AES_128_GCM_SHA256 (dh 1024) - A
| TLS_DHE_RSA_WITH_AES_256_CBC_SHA (dh 1024) - A
| TLS_DHE_RSA_WITH_AES_256_CBC_SHA256 (dh 1024) - A
| TLS_DHE_RSA_WITH_AES_256_GCM_SHA384 (dh 1024) - A
| TLS_ECDHE_RSA_WITH_AES_128_CBC_SHA (secp256r1) - A
| TLS_ECDHE_RSA_WITH_AES_128_CBC_SHA256 (secp256r1) - A
| TLS_ECDHE_RSA_WITH_AES_128_GCM_SHA256 (secp256r1) - A
| TLS_ECDHE_RSA_WITH_AES_256_CBC_SHA (secp256r1) - A
| TLS_ECDHE_RSA_WITH_AES_256_CBC_SHA384 (secp256r1) - A
| TLS_ECDHE_RSA_WITH_AES_256_GCM_SHA384 (secp256r1) - A
| compressors:
| NULL
| cipher preference: client
| warnings:
| Key exchange (dh 1024) of lower strength than certificate key
|_ least strength: A
Hope that helps