
According to Apple, attempting to synchronously executing a work item on main queue results into a dead-lock.
So writing DispatchQueue.main.sync {}
can lead to deadlock condition as all the UI operations performed by app is performed on main queue unless we manually switch some task on the background queue. This also answer your question regarding on which thread CellForRowAt is called. All the methods related to UI operation or UIkit are called from main thread
Performing a task synchronously means blocking a thread until the task is not completed and in this case you are attempting to block main thread on which the system / app would be already performing some task and that can lead to deadlock. Blocking main thread is not at all recommended and thats why we need to switch asynchronously to a background thread so that main thread is not blocked.
To read more you can visit the following link:
https://developer.apple.com/documentation/dispatch