You would typically only want one config file. If this is a web application, it will be the web.config file. You can read this from a class library by adding a reference to System.Configuration
and using ConfigurationManager.AppSettings.Settings["settingkey"]
to access it.
If you really need to access a separate app.config file, you will need to know the path to it and use something like:
ExeConfigurationFileMap map = new ExeConfigurationFileMap();
map.ExeConfigFilename = pathToAppConfigFile;
System.Configuration.Configuration config = ConfigurationManager
.OpenMappedExeConfiguration(map, ConfigurationUserLevel.None);
setting = config.AppSetting.Settings["settingkey"];