You have gotten many good answers already, including the use of dark.exe
from the WiX toolkit. By downloading the WiX source code you should be able to get the code you need ready-made from there. I assume you may already have done this.
Chris has already linked to the DTF code you can check, but here is a link directly to dark.exe as well: https://github.com/wixtoolset/wix3/tree/develop/src/tools/dark. I would try both. This is C#, you seem to want native.
UPDATE: Before I get to the Win32 features you can use, check out this little summary of the C# DTF features: How to programmatically read the properties inside an MSI file?
Native Win32 functions: The database functions to deal with an MSI file can be found on MSDN (this is to deal with the MSI file as a database). There are also MSI Installer Functions (used to deal with the MSI file as an actual installer).
You can certainly find good examples of native code for this with a good Google search. Have fun!
BTW: It would help with a description of the actual problem you are trying to solve as well as what you need technically. There could - as always - be less involved ways to achieve what you need. Unless you are writing a security software or malware scanner or something super-involved.
And so it is clear: WiX's dark.exe
fully decompiles MSI files into WiX source files and the resource files used to build them - you can then text and binary compare the various types of content (text compare for tables, binary compare for binaries, etc...). The process to do so via command line is described in the following answer: How can I compare the content of two (or more) MSI files? (this is about comparing MSI files, but one option to do so is to decompile them - see section on dark.exe
- just for reference for others who find your question).
I like to link things together so we can find content easily at a later point in time. Strictly speaking it doesn't seem necessary here, you have what you need I think but others could perhaps benefit from some further links. Here are some related links: