As the comments say, you have a serialized array. But there are two potential problems with using unserialize.
You should not use unserialize on untrusted data. There's a big warning in the documentation. If you don't trust the data fully, I suggest a safer alternative like _safe_unserialize
used by myBB. You can find it on github.
Second your string looks corrupted in one place. It should be s:10:"Post Title";
. That means that unserialize/safe_unserialize will throw errors. To fix that, take a look at the first two answers of this question.
After you did all that, and stored the unserialized data in - let's say $arr - you can access the post title via: $array[0]['data']
.