As far as I'm aware, there's no IDE for developing in RPG that doesn't require a connection to an AS400. So, in order to really learn how to develop in RPG, you must be able to access an AS400, which is a little inconvenient for newcomers.
There is a free IDE called "RPG Next Gen Editor" that's built on the Eclipse platform. You can check it out here, but as I mentioned above, it requires a connection to an AS400. It's similar in function to IBM's Rational Developer, which is far superior, but the price tag is much better!
https://sourceforge.net/projects/rpgnextgen/
Finding resources online for "RPG" can be a little tricky because most of the results you end up getting are for RPG role-playing games. When searching Google for resources on RPG programming, it's helpful to search instead for "RPGLE", which is short for ILE RPG IV.
A good place to start might be here in the IBM wiki:
https://ibm.biz/rpgCafe_Freeform_Rpg_Tutorial
Note that this tutorial is VERY basic.
Also see Scott Klement's "How to Learn" page, which lists a few books you can buy that will really help you out if you get the job. I HIGHLY recommend the "Programming in RPG IV" book by Bryan Meyers and Jim Buck. This was the textbook used in a class I took, but it's actually set up in such a manner that you could easily read through the book and teach yourself RPG in a few weeks time. It teaches file design, display file design, and RPG programming, so it's really the whole package with plenty of tutorials and sample programs.
https://www.scottklement.com/rpg/howtolearn.html
Good luck, and welcome to the world of RPG!