Try this:
Stamp.Text = BlogComment.Date.ToString("yyyy-MM-ddTHH\\:mm\\:ss.fffffffzzz");
Or
Stamp.Text = BlogComment.Date.ToString(@"yyyy-MM-ddTHH:mm:ss.fffffffzzz");
My mistake: The \
is indeed required, because it might be a custom format specifier.
And if you just want the current time, use
Stamp.Text = DateTime.UtcNow.ToString(@"yyyy-MM-ddTHH\:mm\:ss.fffffffzzz");
UtcNow is static. It should not be accessed from an instance. It should be accessed from the class itself.
Alternatively, you might want:
Stamp.Text = BlogComment.Date.ToUniversalTime().ToString(@"yyyy-MM-ddTHH\:mm\:ss.fffffffzzz");
This would get you the universal time of the Date in BlogComment.