This depends on the CPU, and on what instructions your compiler will generate. Some CPUs will happily perform unaligned loads (basically, they read the two halves and recombine them for you). Some will silently return corrupted data, and some will generate an exception and cause your program to crash immediately. Sometimes a CPU will have multiple instructions that can load and store data, some allow unaligned access, some don't.
The best way to find out what is happening on your CPU is to test it out. Or, look at the assembly generated by your compiler, and look up those assembly instructions in your CPU's manual to find out what it is going to do.
See this question for more information if you have an Intel or AMD CPU: What's the actual effect of successful unaligned accesses on x86?