As mentioned in the official documentation of Google chrome browser link, it uses
either
Chrome or CriOS (for iOS)
in user agent header. So you need to check for both in case you wanted to test for chrome browser
The rule for it can be following
RewriteCond %{HTTP_USER_AGENT} ^.*(Chrome|CriOS).*$
RewriteRule .* - [L]
RewriteRule .* URL [R,L]
The regex is working and can be verified at regex tester
However there is no single approach through which you can be sure that the browser is official Chrome because many other browsers are also using chrome in their user agent header to ride the popularity of Google Chrome like
Dragon,Edge,Flock,Iron,Kinza,Maxthon (to name a few)
You can go to http://www.useragentstring.com/ to find the user agents of other browsers that uses chrome in their user agent header and exclude them in the rewrite rule.
So the final rewrite rule can be following
RewriteCond %{HTTP_USER_AGENT} ^.*(Chrome|CriOS).*$
RewriteCond %{HTTP_USER_AGENT} !^.*(Aviator|ChromePlus|coc_|Dragon|Edge|Flock|Iron|Kinza|Maxthon|MxNitro|Nichrome|OPR|Perk|Rockmelt|Seznam|Sleipnir|Spark|UBrowser|Vivaldi|WebExplorer|YaBrowser).*$
RewriteRule .* - [L]
RewriteRule .* URL [R,L]
The browser list is from link