Edit Start
1) If you want to show all the tables in all the data bases please populate the combo box the same.
refer: How do I list all tables in all databases in SQL Server in a single result set?
2) Or you can provide another combo box to display list of data bases, prior to tables combo box, once user chooses a DB name, pass it to the query. This is useful choice, as there is a possibility of having a table with same name in two data bases. (Eg: t_users in db_1 and db_2)
3) If you have confined to two data bases, use where clause in the above said (1)
Edit end
If you want to access multiple data bases of one server and one instance, It is enough to have one connection to one database in that server and instance, provided user has access to those DBs. You can query any data base if all DB are in same server and instance, see example below.
SELECT a.ID, b.ID
FROM Database1.dbo.table1 a
INNER JOIN Database2.dbo.table2 b on a.ID = b.ID
In your case, you can have your query of stored procedure similar to below queries.
select *
from sys.tables --to fetch list of tables from the DB which you app connected to
select *
from IAMS_Discr_Complaints.sys.tables --to fetch tables from another DB on the same server