This is identical scenario to Cannot call non W3C standard command while in W3C mode (Selenium::WebDriver::Error::UnknownCommandError) with Selenium ChromeDriver in Cucumber Ruby but the solutions don't seem to apply directly to C# so rather than ask in the comments I thought it more appropriate to start a separate thread.
After Chrome upgraded to v.76 I had to update Chromedriver.exe to v.76. I immediately started getting the error in the title. Searching for the issue you find that starting with v75 "ChromeDriver now runs in W3C standard compliant mode by default." The suggested workaround is to "specifying w3c:false in ChromeOptions".
I'm asking for help on how to specify this in .net Webdriver
I use ChromeOptions options = new ChromeOptions();
and then I update options as needed before doing driver = new ChromeDriver(@"c:\WebDriver", options);
I haven't been able to figure out how to add the 'w3c',false as, for instance, add_experimental_option
doesn't exist in C# Webdriver.