To get the raw frames you just need to run the request in debug mode.
That would be something like this:
from pymodbus.client.sync import ModbusTcpClient
import logging
FORMAT = ('%(asctime)-15s %(threadName)-15s '
'%(levelname)-8s %(module)-15s:%(lineno)-8s %(message)s')
logging.basicConfig(format=FORMAT)
log = logging.getLogger()
log.setLevel(logging.DEBUG)
ipAddress = '10.130.14.174'
registerToRead = 3000
client = ModbusTcpClient(ipAddress, port=502)
connection = client.connect()
response = client.read_holding_registers(registerToRead, 1, unit=1)
If you are running this code from the Python console now you should see something similar to this:
2019-10-08 13:10:42,872 MainThread DEBUG transaction :111 Current transaction state - TRANSACTION_COMPLETE
2019-10-08 13:10:42,872 MainThread DEBUG transaction :116 Running transaction 3
2019-10-08 13:10:42,872 MainThread DEBUG transaction :215 SEND: 0x0 0x3 0x0 0x0 0x0 0x6 0x1 0x3 0x0 0x1 0x0 0x1
2019-10-08 13:10:42,872 MainThread DEBUG sync :73 New Transaction state 'SENDING'
2019-10-08 13:10:42,872 MainThread DEBUG transaction :224 Changing transaction state from 'SENDING' to 'WAITING FOR REPLY'
2019-10-08 13:10:42,873 MainThread DEBUG transaction :300 Changing transaction state from 'WAITING FOR REPLY' to 'PROCESSING REPLY'
2019-10-08 13:10:42,873 MainThread DEBUG transaction :229 RECV: 0x0 0x3 0x0 0x0 0x0 0x5 0x1 0x3 0x2 0x0 0x14
2019-10-08 13:10:42,873 MainThread DEBUG socket_framer :147 Processing: 0x0 0x3 0x0 0x0 0x0 0x5 0x1 0x3 0x2 0x0 0x14
2019-10-08 13:10:42,873 MainThread DEBUG factory :266 Factory Response[ReadHoldingRegistersResponse: 3]
2019-10-08 13:10:42,873 MainThread DEBUG transaction :379 Adding transaction 3
2019-10-08 13:10:42,873 MainThread DEBUG transaction :390 Getting transaction 3
2019-10-08 13:10:42,873 MainThread DEBUG transaction :189 Changing transaction state from 'PROCESSING REPLY' to 'TRANSACTION_COMPLETE'
>>>
If you want more details or you need to process more than a couple of frames I would advise to install Wireshark which is very powerful. If you need to do the same with Modbus over serial you can try SerialPCAP.
EDIT: This is probably something you don't need at the moment but in case you don't have access to either side of a Modbus serial link you can tap on the bus or use a software sniffer as I explained here, here and here.
For Modbus TCP, I'm not aware of any easy technique to monitor traffic with Wireshark if you don't have access to either side of the link or to the network switch.