df1
A B C D
0 26 39 7 44
df2
C D G H
0 12 40 26 64
pd.concat([df1, df2],axis=0, ignore_index=True)
Please do not suggest joins as this column are dynamic desired output looks like this
A B C D E F G H
0 26 39 7 44 NaN NaN NaN NaN
1 NaN NaN 12 40 26 64 NaN NaN