In order to obtain the position, initially, you should get the position of caret at the start of the paragraph. Then, you get the rectangle of bounding box. The Y property of the rectangle can scroll the paragraph at the first of the RichTextBox.
private void RichTextBox_OnLoaded(object sender, RoutedEventArgs e)
{
// Get the paragraph block text
var textBlock = RichTextBox.Document.Blocks.ElementAt(2);
//get the caret position of the start of the paragraph
var startOfTextBlock = textBlock.ContentStart;
// get the the character rectangle
Rect charRect = startOfTextBlock.GetCharacterRect(LogicalDirection.Forward);
// set the the vertical offset ot the Y position of the rectangle
RichTextBox.ScrollToVerticalOffset(charRect.Y);
}