From https://www.rfc-editor.org/rfc/rfc5970#section-6:
"The following options have been assigned by the IANA from the option
number space defined in Section 24 of the DHCPv6 RFC [RFC3315]."
So, I would suggest that
https://www.iana.org/assignments/dhcpv6-parameters/dhcpv6-parameters.xhtml#processor-architecture is probably a good source.
Yes, this is DHCPv6, not DHCPv4, but no one appears to have cared enough to supersede rfc4578 with an updated version.
Having reached that conclusion, I peeked in UEFI 2.8. In Table 210. PXE Tag Definitions for EFI, the description for Client System Architecture
is:
Type (2) Type is a two byte, network order, field that identifies the
processor and programming environment of the client system. For the
various architecture type encodings, see the table "Processor
Architecture Types" at “Links to UEFI-Related Documents” (http://uefi.org/uefi)
under the heading “Processor Architecture Types
That link in fact points to the IANA page again.