This really has nothing to do with structs; it is simply the usual issue of passing data into a view controller on creation and passing data back from that view controller on destruction. It happens that in your case you are positing that this is the "same" data — i.e. you pass a Post to the detail view controller and you pass a Post back from the detail view controller — but that is just a contingent fact.
So, to answer the question as formulated, you would use any of the usual techniques. The detail view controller would need to pass the modified Post back to the master view controller. It could use a Notification or (more directly) you could use the standard protocol-and-delegate architecture.
On the other hand, if Post is the basis of your app's data, it would not be unreasonable to argue that the premise itself is flawed: this should have been a class all along, not a struct, exactly so that the data can be maintained in a central place and references to it can be maintained in different places.
Indeed, if things are more complex, you might have the app's data (including the Post) live in some third location off in model-data-space, and have all view controllers send a notification up to the data when they change it and have the data send a notification down to all view controllers in response (that is what Ralf Ebert's answer quite reasonably suggests). That sort of thing is a lot easier nowadays because (in iOS 13) we have observable objects and the Combine framework.