MIME types are just a way to identify the type of a file. Typically, there are two ways to figure out what the type of a file is:
Look at the file extension. For example, a pdf is usually saved as file.pdf
ending with the extension pdf. This is a hint that the type of the file is pdf file. However, you can change the name of the file and simply change its extension to something else. So, the name of a file does not necessarily have to indicate its type
Look at the contents of the file and try to guess based on how its arranged in binary.
Most binary files have very specific representation inside a file. For example, if you open a pdf file in a notepad (or any text editing program), you will find that it starts with %PDF-. Followed by some numbers and potentially weird characters. This tells you that this is a pdf type.
Why is this useful? Files are simply saved as blocks of binary data. However, certain files can only be opened by certain programs (for example, music files can't be "opened" by text editors, it can only be played with a music player). By figuring out the MIME type of a file, you can understand how to interpret the data in the file (for example, text, image, video, audio are common mime types). Then, you can use the correct software to use the file.