As per AWS documentation here - You cannot switch roles when you sign in as the AWS account root user.
If we go by AWS best practices i.e. not to use root user to perform actions, this restriction makes sense & supports why AWS does not allow role switch as root user. However, when using a Bucket policy, a root user in one account can access a Bucket in another account & AWS does not seem restricting that unlike roles (Technically, both are cross account actions using resource policies).
Why does this 'root user restriction' apply only for roles and not buckets - Any security reasons?