I have a dataframe called 'df':
Value Num
0 alpha 5
1 bravo 6
2 charlie 7
And a Series called 'series_to_add':
New Value
0 alpha
1 bravo
2 delta
How can I combine the unique values of the series into the existing dataframe to get something like this:
Value Num
0 alpha 5
1 bravo 6
2 charlie 7
3 delta nan