There is a way to change The User-Agent of web browser control and it works! I changed the User-Agent by using the following code:
WebBrowser1.Navigate("https://example.com/file.php", Nothing, Nothing, "User-Agent: Your User-Agent" + vbCrLf)
It works, But the problem is that this code works one time!
For example if you entered to this site "https://example.com/login.php" and the site has referred you to another page! The second page will use the default User-Agent of Microsoft visual studio
Let me clarify this,The problem is that the code shown above cannot use the User-Agent more than once, After the site redirect you to another page the web browser will use the default User-Agent