You could put the username and password into a separate section and encrypt this section only. For example:
<?xml version="1.0" encoding="utf-8" ?>
<configuration>
<configSections>
<section name="secureAppSettings" type="System.Configuration.NameValueSectionHandler, System, Version=4.0.0.0, Culture=neutral, PublicKeyToken=b77a5c561934e089" />
</configSections>
<appSettings>
<add key="Host" value="www.foo.com" />
<add key="Token" value="qwerqwre" />
<add key="AccountId" value="123" />
<add key="DepartmentId" value="456" />
<add key="SessionEmail" value="foo@foo.com" />
<add key="DefaultFolder" value="789" />
</appSettings>
<secureAppSettings>
<add key="userName" value="s752549"/>
<add key="userPassword" value="Delhi@007"/>
</secureAppSettings>
</configuration>
and then use aspnet_regiis
For Ex:
aspnet_regiis -pef secureAppSettings . -prov DataProtectionConfigurationProvider