Other than no jQuery there at all, you're defining the array as an array of objects. Define an object like this:
var pStData = {};
pStData['WV'] = {geom: 'xxx'};
pStData['TX'] = {geom: 'yyy'};
Then you can access simply by
var sGeom = pStData['WV'].geom;
You can also access it via
var sGeom = pStData.WV.geom;
Of course you don't need to define the object if you're only looking up a string value, for example this would work just as well.
var pStData = {};
pStData['WV'] = 'xxx';
pStData['TX'] = 'yyy';
However, defining it as an object does future proof your code, should you need to add extra data values later. Never be afraid to do a bit of future proofing, it can save a lot of work later.