You can download a free copy SQL Express Management Studio (SSMS).
SSMS has the ability to connect to both full blown SQL, SQL Express, and SQL CE databases.
Within SSMS you can right click on the table and use the wizard to move data back and forth. Or create scripts that will generate the raw table structures that exist in MS SQL, SQL Express and allow you to move them to SQL CE.
The primary wizard you'll probably use in SSMS to move data from an Access table to a SQL, or SQL CE table is called SQL Server Import/Export Wizard.
The learning curve on these wizards is pretty minimal. As your needs grow more advanced and the things you want to do get a little more fancy you'll find that scripting and the tsql language is where you'll want to dedicate some time to learning. But this should get you started with the question at hand.