This may no be optimal, but is very straightforward:
from itertools import chain, combinations
def power_set(iterable):
"""power_set([1,2,3]) --> () (1,) (2,) (3,) (1,2) (1,3) (2,3) (1,2,3)"""
source = list(iterable)
return chain.from_iterable(combinations(source, r) for r in range(1, len(source) // 2 + 1))
def complement(source, universe):
return tuple(set(universe) - set(source))
lst = ['a', 'b', 'c', 'd', 'e', 'f']
result = set(frozenset({si, complement(si, lst)}) for si in power_set(lst))
for s, c in result:
print(s, c)
Output
('a', 'd', 'e') ('f', 'c', 'b')
('f', 'a', 'c', 'b') ('d', 'e')
('b', 'e') ('d', 'f', 'a', 'c')
('a', 'b', 'f') ('d', 'e', 'c')
('e', 'd', 'a', 'f', 'b') ('c',)
('c', 'f') ('d', 'a', 'e', 'b')
('d', 'f') ('a', 'e', 'b', 'c')
('d',) ('e', 'c', 'a', 'f', 'b')
('f', 'a', 'e', 'c') ('b', 'd')
('e', 'c', 'd', 'a', 'b') ('f',)
('b', 'c', 'd') ('f', 'a', 'e')
('a', 'b', 'e') ('d', 'f', 'c')
('b', 'c') ('d', 'f', 'a', 'e')
('f', 'a', 'b') ('c', 'd', 'e')
('d', 'e', 'b', 'c') ('a', 'f')
('c', 'd', 'f') ('a', 'e', 'b')
('e', 'c', 'd', 'f', 'b') ('a',)
('a', 'c') ('d', 'f', 'e', 'b')
('f', 'e', 'c') ('a', 'b', 'd')
('a', 'd') ('f', 'e', 'b', 'c')
('b', 'c', 'e') ('d', 'f', 'a')
('a', 'c', 'e') ('d', 'f', 'b')
('d', 'e', 'f') ('a', 'c', 'b')
('a', 'c', 'd') ('f', 'e', 'b')
('d', 'f', 'e', 'c') ('a', 'b')
('f', 'a', 'e', 'b') ('c', 'd')
('d', 'a', 'c') ('b', 'e', 'f')
('a', 'e') ('d', 'f', 'c', 'b')
('a', 'b', 'c') ('d', 'f', 'e')
('a', 'd', 'f') ('e', 'b', 'c')
('d', 'e', 'b') ('a', 'c', 'f')
('c', 'd', 'a', 'f', 'b') ('e',)
('b',) ('e', 'c', 'd', 'a', 'f')
('e', 'f') ('d', 'a', 'c', 'b')
('d', 'c', 'b') ('a', 'e', 'f')
('b', 'f') ('d', 'a', 'e', 'c')
('d', 'a', 'e') ('b', 'c', 'f')
('b', 'd', 'e') ('f', 'a', 'c')
('a', 'e', 'c') ('b', 'd', 'f')
('c', 'e') ('d', 'f', 'a', 'b')
('d', 'a', 'b') ('c', 'e', 'f')