My best guess would be that you can't (which is in line with this answer). I tried a couple of options and got the same error with in-built classes. As per Chris_Rands' answer, you can always create a Class inheriting from the in-built object in question.
>>> int.__add__ = int.__mul__
int.__add__ = int.__mul__
Traceback (most recent call last):
File "<stdin>", line 1, in <module>
TypeError: can't set attributes of built-in/extension type 'int'
and
>>> dict.__add__ = list.__add__
dict.__add__ = list.__add__
Traceback (most recent call last):
File "<stdin>", line 1, in <module>
TypeError: can't set attributes of built-in/extension type 'dict'
Looks like the error is not a syntax problem but more explicitly you can't redefine built-in methods.