You can create custom objects from qwinsta's output, filter them and use rwinsta to kill the session.
Function Get-TSSessions
{
param (
[Parameter(Mandatory = $true, Position = 0 )]
[String]$ComputerName
) # End Parameter Block
qwinsta /server:$ComputerName |
ForEach-Object{
If($_ -notmatch "SESSIONNAME")
{
New-Object -TypeName PSObject -Property `
@{
"ID" = [Int]$_.SubString(41,05).Trim()
"ComputerName" = $Computer
"User" = $_.SubString(19,22).Trim()
"State" = $_.SubString(47,08).Trim()
}
}
}
} # End Function Get-TSSessions
Get-TSSessions -ComputerName <ServerName> |
Where-Object{$_.User -eq "SomeUser"} |
ForEach{ & "rwinsta /Server:$($_.ComputerName) $($_.ID)" }
Obviously, you can improve by wrapping up the rwinsta command in its own function. At the moment I only have reporting work written around this sort of thing, so in the spirit of answering the question without writing the whole thing, this should get you through.
Also, I believe there are a number of scripts and functions available for this on the PowerShell Gallery. In fact, I think there were functions Get/Stop-TerminalSession
in the PowerShell Community Extensions, which you can install as a module.