If (like in your template) it's enough to filter on the value-element, then this wil work.
<xsl:stylesheet
version="2.0"
xmlns:infor="http://schema.infor.com/InforOAGIS/2"
xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"
xmlns:xsl="http://www.w3.org/1999/XSL/Transform"
xmlns:xs="http://www.w3.org/2001/XMLSchema"
exclude-result-prefixes="#all">
<xsl:output method="xml" encoding="UTF-8" indent="no" byte-order-mark="no"/>
<xsl:strip-space elements="*"/>
<xsl:template match="@*|node()">
<xsl:copy>
<xsl:apply-templates select="@*|node()"/>
</xsl:copy>
</xsl:template>
<xsl:template match="infor:Concur_LN_ServiceData">
<xsl:if test="not(following-sibling::infor:Concur_LN_ServiceData[infor:Value=current()/infor:Value])">
<xsl:copy>
<xsl:apply-templates select="@*|node()"/>
</xsl:copy>
</xsl:if>
</xsl:template>
</xsl:stylesheet>
There were 2 problems in your xslt:
Namespace: "http://schema.infor.com/InforOAGIS/2" had no prefix: see this example
Your XPath: following::Concur_LN_ServiceData[Concur_LN_ServiceData
cannot find anything because there is no Concur_LN_ServiceData
with an element Concur_LN_ServiceData
And declare namespaces that you actually use....but that is just my personal preference
EDIT
If you are dealing with large xml, it is better to use for-each-group (like @michael.hor257k is telling):
<xsl:stylesheet
version="2.0"
xmlns:infor="http://schema.infor.com/InforOAGIS/2"
xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"
xmlns:xsl="http://www.w3.org/1999/XSL/Transform"
xmlns:xs="http://www.w3.org/2001/XMLSchema"
exclude-result-prefixes="#all">
<xsl:output method="xml" encoding="UTF-8" indent="no" byte-order-mark="no"/>
<xsl:strip-space elements="*"/>
<xsl:template match="@*|node()">
<xsl:copy>
<xsl:apply-templates select="@*|node()"/>
</xsl:copy>
</xsl:template>
<xsl:template match="infor:DataArea">
<xsl:copy>
<xsl:apply-templates select="infor:Show"/>
<xsl:for-each-group select="infor:Concur_LN_ServiceData" group-by="infor:Value">
<xsl:sequence select="current-group()[1]"/>
</xsl:for-each-group>
</xsl:copy>
</xsl:template>
</xsl:stylesheet>