Here is what I have so far that populates all the values from the cells into my combo box:
Private Sub UserForm_Initialize()
'Extracts Locations From Cells
Dim ws As Worksheet
Set ws = Worksheets("B")
Dim Location As Range
For Each Location In ws.Range("E7:E100")
With Me.Combobox
.AddItem Location.Value
End With
Next Location
End Sub