So if I learn Spring in Kotlin,
You will learn Spring, using Kotlin. Spring is a JVM framework, the API you will interact with is the same in Java or Kotlin.
can I easily switch to Java Spring?
You can even mix Kotlin and Java in the same project and it will work, however I do not advise doing so. It's also possible to translate from Java -> Kotlin (IntelliJ does this if you paste java code in a .kt file!) or Kotlin -> Java, however the output code is not very nice :)
do companies care?
You should ask this to your superiors, it depends a lot on the company policies. In general, Java has a much bigger market specially for big companies which move slow and are afraid of changes. Kotlin is mostly sought for Android development, on which Spring is not recommended.
Nevertheless, if you already know Java and just are interesting only in learning Spring I suggest you use Java for this.
do I miss out on other, more important skills that I can learn
instead?
I'm also a Java and Kotlin programmer for the backend and I can say that the Kotlin opportunities are mostly for Android development, it's odd to find roles for Kotlin backend development.
If you're looking to prepare for your first job I'd say don't worry on learning a new language, Java has a lot of opportunities. I suggest you focus instead on learning the other important aspects of development (databases, cloud services, containers, testing, software engineering, networking, etc.) those will be far more valuable than knowing two very similar programming languages.