This is the error that is being displayed in the console output. Given the specific path to the python config. Also specified the path in both system and user environment variables.
Running as SYSTEM
Building on master in workspace C:\Windows\system32\config\systemprofile\AppData\Local\Jenkins\.jenkins\workspace\pyproj
[pyproj] $ python C:\Windows\TEMP\jenkins1868508063547381339.py
The system cannot find the file specified
FATAL: command execution failed
java.io.IOException: CreateProcess error=2, The system cannot find the file specified
at java.base/java.lang.ProcessImpl.create(Native Method)
at java.base/java.lang.ProcessImpl.<init>(ProcessImpl.java:487)
at java.base/java.lang.ProcessImpl.start(ProcessImpl.java:154)
at java.base/java.lang.ProcessBuilder.start(ProcessBuilder.java:1107)
Caused: java.io.IOException: Cannot run program "python" (in directory "C:\Windows\system32\config\systemprofile\AppData\Local\Jenkins\.jenkins\workspace\pyproj"): CreateProcess error=2, The system cannot find the file specified
at java.base/java.lang.ProcessBuilder.start(ProcessBuilder.java:1128)
at java.base/java.lang.ProcessBuilder.start(ProcessBuilder.java:1071)
at hudson.Proc$LocalProc.<init>(Proc.java:253)
at hudson.Proc$LocalProc.<init>(Proc.java:222)
at hudson.Launcher$LocalLauncher.launch(Launcher.java:996)
at hudson.Launcher$ProcStarter.start(Launcher.java:508)
at hudson.tasks.CommandInterpreter.perform(CommandInterpreter.java:144)
at hudson.tasks.CommandInterpreter.perform(CommandInterpreter.java:92)
at hudson.tasks.BuildStepMonitor$1.perform(BuildStepMonitor.java:21)
at hudson.model.AbstractBuild$AbstractBuildExecution.perform(AbstractBuild.java:808)
at hudson.model.Build$BuildExecution.build(Build.java:199)
at hudson.model.Build$BuildExecution.doRun(Build.java:164)
at hudson.model.AbstractBuild$AbstractBuildExecution.run(AbstractBuild.java:516)
at hudson.model.Run.execute(Run.java:1889)
at hudson.model.FreeStyleBuild.run(FreeStyleBuild.java:43)
at hudson.model.ResourceController.execute(ResourceController.java:100)
at hudson.model.Executor.run(Executor.java:433)
Build step 'Execute Python script' marked build as failure
Finished: FAILURE