At first I thought it was a simple matter of there not being a trailing newline, and the new row being appended on the same line, right after the last row, but I can see what looks like a row's worth of empty columns between them.
This whole appending thing looks tricky. If you don't have to use Python, and can use a command-line tool instead, I recommend GoCSV.
Here's a sample file based on your screenshot I mocked up:
base.csv
Date,Asset,Fear,Anger,Anticipation,Trust,Surprise,Sadness,Disgust,Joy,Positivity,Negativity
Nov 1,5088,0.84,0.58,0.73,1.0,0.26,0.89,0.22,0.5,0.69,0.59
Nov 2,4580,0.0,0.88,0.7,0.71,0.57,0.78,0.2,0.22,0.21,0.17
Nov 3,2469,0.72,0.4,0.66,0.53,0.65,0.64,0.67,0.78,0.54,0.32,,,,,,,
I'm calling it base because it's the file that will be growing, and you can see it's got a problem on the last line: all those extras commas (I don't know how they got there ♂️).
The first step will be to clean it, and trim those pesky extra commas:
% gocsv clean base.csv > tmp
% mv tmp > base.csv
and now base.csv looks like:
Date,Asset,Fear,Anger,Anticipation,Trust,Surprise,Sadness,Disgust,Joy,Positivity,Negativity
Nov 1,5088,0.84,0.58,0.73,1.0,0.26,0.89,0.22,0.5,0.69,0.59
Nov 2,4580,0.0,0.88,0.7,0.71,0.57,0.78,0.2,0.22,0.21,0.17
Nov 3,2469,0.72,0.4,0.66,0.53,0.65,0.64,0.67,0.78,0.54,0.32
Here's another set of data to append, sample2.csv:
Date,Asset,Fear,Anger,Anticipation,Trust,Surprise,Sadness,Disgust,Joy,Positivity,Negativity
Nov 4,6040,0.69,0.89,0.72,0.44,0.21,0.15,0.03,0.63,0.78,0.42
Nov 5,7726,0.72,0.12,0.95,0.6,0.88,0.1,0.43,1.0,1.0,0.68
Nov 6,9028,0.87,0.34,0.46,0.57,0.15,0.3,0.8,0.32,0.17,0.42
Nov 7,3544,0.16,0.9,0.37,0.8,0.67,0.0,0.11,0.72,0.93,0.35
GoCSV's stack command will do this job:
% gocsv stack base.csv sample2.csv > tmp
% mv tmp base.csv
and now base.csv looks like:
Date,Asset,Fear,Anger,Anticipation,Trust,Surprise,Sadness,Disgust,Joy,Positivity,Negativity
Nov 1,5088,0.84,0.58,0.73,1.0,0.26,0.89,0.22,0.5,0.69,0.59
Nov 2,4580,0.0,0.88,0.7,0.71,0.57,0.78,0.2,0.22,0.21,0.17
Nov 3,2469,0.72,0.4,0.66,0.53,0.65,0.64,0.67,0.78,0.54,0.32
Nov 4,6040,0.69,0.89,0.72,0.44,0.21,0.15,0.03,0.63,0.78,0.42
Nov 5,7726,0.72,0.12,0.95,0.6,0.88,0.1,0.43,1.0,1.0,0.68
Nov 6,9028,0.87,0.34,0.46,0.57,0.15,0.3,0.8,0.32,0.17,0.42
Nov 7,3544,0.16,0.9,0.37,0.8,0.67,0.0,0.11,0.72,0.93,0.35
This can be scripted and simplified like this:
% gocsv clean base.csv > base
% gocsv clean sample.csv > sample
% gocsv stack base sample > base.csv
% rm base sample