var possibleKeyCodes = [ 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90 ];
console.log(possibleKeyCodes[0].key);
Your array is an array of numbers. You are trying to treat an element of this array as it is an object with key
property
If you need the ascii repreentation of that number you can do it like that
console.log(String.fromCharCode(possibleKeyCodes[0]))
Or as a snippet
var possibleKeyCodes = [ 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90 ];
console.log(String.fromCharCode(possibleKeyCodes[0]))