d = {}
for sublist in orig_list:
new_key, new_value = sublist[0], sublist[1:]
d[new_key] = new_value
Since you're a beginner, it's best to take a beginner's approach...
You want a dictionary, so you start by creating an empty one.
Then we'll iterate over the list you've been given, and for each sublist of the list, we'll take the first element and make it a new key in the dictionary. And we'll take the remaining elements of the list and make them a new value of the new key.
When you're done processing, you'll have the dict that you want.
Since others mention a "dictionary comprehension," I'll add that to my answer, as well. A dict comp. that corresponds to what I've done above could be:
d = {sublist[0]: sublist[1:] for sublist in orig_list}
But, as I've mentioned below in my comments, I don't think a dictionary comprehension is appropriate for a beginner programmer. My first solution is the better one.