For a free tool I recommend schema spy, http://schemaspy.sourceforge.net/.
It needs Java Runtime.
Look to http://schemaspy.sourceforge.net/sample/relationships.html to see diagrams it generate.
This tool is also more suitable to automatic build scripts.
simple usage with oracle hr template is given below.
SET JDBC_ORACLE_JAR=C:\oracle\product\10.2.0\client_1\jdbc\lib\ojdbc14.jar
SET CONNECTION_USERNAME=hr
SET CONNECTION_PASSWORD=hr
SET TNS_DATABASE_NAME=orcl
SET SCHEMA_NAME=HR
SET TABLE_NAME='EMP'
SET OUTPUT_NAME=HR_EMP
java -jar schemaSpy_5.0.0.jar -dp %JDBC_ORACLE_JAR% -db %TNS_DATABASE_NAME% -o schemaOutput%OUTPUT_NAME% -u %CONNECTION_USERNAME% -p %CONNECTION_PASSWORD% -i %TABLE_NAME%.* -schemas %SCHEMA_NAME% -hq -noviews -loglevel severe
java -jar schemaSpy_5.0.0.jar -dp %JDBC_ORACLE_JAR% -db %TNS_DATABASE_NAME% -o schemaOutput%OUTPUT_NAME% -u %CONNECTION_USERNAME% -p %CONNECTION_PASSWORD% -schemas %SCHEMA_NAME% -hq -noviews -loglevel severe
First one will give you diagram with tables starting with EMP .
Second one will give you diagram with all tables in hr schema .