Working on the assumption that your Windows app and your server are one the same domain I would suggest you use a publish/subscribe pattern for this type of interaction. You could use something along the lines of the IDesign sample which is available on their website. Essentially your Windows app is subscribing to events which are generated by your mobile application sending a posting to your server. Your publisher will then push the event to your Windows application.
To accomplish this your connection to the server/publisher needs to be always open. This is best achieved with tcpBinding as it is bi-directional and allows you to set high timeouts (effectively infinity).
If you cannot use TCP then your job has become a little harder. Using a duplex channel is a little problematic because you have to monitor the channel as well, because neither side will notifiy the other if the channel closes. You will only find out when you try to use it. This can still happen with the TCP connection of course but its a bit more stable that using http.
The other alternative is to use MSMQ binding. This will guarantee the delivery of your message because you are interacting via MSMQ rather than a communication channel such as http or tcp. In this instance you wouldn't even need the pub/sub framework, you could just have the service that receives your mobile posting send on a message to the queue, which your Windows application is monitoring. The upside to using the framework is that you can have multiple applications listening for the same event.
HTH.