You need to add a background page in the manifest file and the appropriate permissions in the manifest so the background page can access the webRequest APIs. See this example: chrome.webRequest not working?
As Mihai mentioned, if you need to have the content script perform the action, check this page out: https://developer.chrome.com/extensions/messaging
Add this to your content script (you can change greeting to action and hello to which action the background script should perform):
chrome.runtime.sendMessage({greeting: "hello"}, function(response) {
console.log(response.farewell);
});
Add this to your background page (you can do if statements and peform different actions based on the message):
chrome.runtime.onMessage.addListener(
function(request, sender, sendResponse) {
console.log(sender.tab ?
"from a content script:" + sender.tab.url :
"from the extension");
if (request.greeting == "hello")
sendResponse({farewell: "goodbye"});
});