This ASSUMES that you have a finite number of rlys values; The only other current way to achieve this is to use DYNAMIC SQL if there are more values. (Searching for link)
Select
sum(case when rly = 'CR' then 1 else 0 end) as "CR",
sum(case when rly = 'ER' then 1 else 0 end) as "ER",
sum(case when rly = 'ECR' then 1 else 0 end) as "ECR",
sum(case when rly = 'ECoR' then 1 else 0 end) as "ECoR",
sum(case when rly = 'NR' then 1 else 0 end) as "NR",
sum(case when rly = 'NCR' then 1 else 0 end) as "NCR",
sum(case when rly = 'SR' then 1 else 0 end) as "SR",
sum(case when rly = 'SCR' then 1 else 0 end) as "SCR",
sum(case when rly = 'SER' then 1 else 0 end) as "SER",
sum(case when rly = 'SECR' then 1 else 0 end) as "SECR",
sum(case when rly = 'WR' then 1 else 0 end) as "WR",
sum(case when rly = 'WCR' then 1 else 0 end) as "WCR",
sum(case when rly = 'Kolkata' then 1 else 0 end) as "Kolkata"
FROM SPAD
EDITED After acceptance to change from count to sum.