Well, I would say first that NoSQL is better at scaling is some situations, but not all.
Full ACID transactions are Atomic, Consistent, Isolated and Durable. If you lose transactions, you will loose some or all of ACID within the datastore.
There are many ways to restore these functions with other asynchronous systems like message queues that themselves are durable. You can shove data onto a durable message queue, pop the data and deal with it in your NoSQL, then, when you can confirm it's stored to your required minimum, you can flag the message as consumed. It's the D in ACID, but distributed and asynchronous. There are ways to ensure the others, but they are often sacrificed to some extent, or moved into another place in the system. With some NoSQL solutions, you just have to move consistency into the application so it doesn't try to store invalid data.
When you start moving away from database driven transactions, you must increase your application testing dramatically to ensure your system doesn't fail (for some values of fail).
There are essentially no situations where transactions and constraints are not important in a system that has both read and write requirements. If they weren't you wouldn't care about your data at all (and some people don't, but regret it later). There are however levels of "caring". It's just a matter of how you end up at ACID or some pseudo-ACID that's "good enough". RDMBS makes caring about your data cheap. NoSQL makes caring about your data expensive, but, it makes scaling cheap(er) (in some cases). There are many companies with multi-terabyte database in RDBMSes, so to say unilaterally that "they don't scale" is simply inaccurate. Multi-terabyte SQL databases however, can cost lots of money, depending on the use case (you can after all just slap a RAID 10 array with a few 3TB drives onto a computer and throw a database engine on it. Might take several minutes to a few hours to do any kind of table scan on a big table, or even indexed look-up though, but if you don't care, it's cheap and multi-terabyte).