As far as I can remember, Hibernate as it is out-of-the box, does not support "package-sanning" to discover your domain classes.
But given that you're integrating Hibernate with Spring MVC, you could annotate your classes (standard JPA + Hibernate specific annotations) and within your Spring context configuration file, specify the package that contains the Hibernate entity classes. Here's how I configured it in a previous project :
<bean id="sessionFactory"
class="org.springframework.orm.hibernate3.annotation.AnnotationSessionFactoryBean">
<property name="dataSource" ref="dataSource" />
<property name="packagesToScan" value="org.springmvc.domain" />
<property name="hibernateProperties">
<props>
<prop key="hibernate.dialect">org.hibernate.dialect.HSQLDialect</prop>
<prop key="hibernate.hbm2ddl.auto">update</prop>
<prop key="show_sql">true</prop>
<prop key="log_level">DEBUG</prop>
</props>
</property>
</bean>
The "packagesToScan" property define the packages that Spring will have Hibernate scan to discover the entity classes.