The main queue does indeed run on the main thread like you say.
The global queues are concurrent queues and from the main page for dispatch_get_global_queue:
Unlike the main queue or queues allocated with
dispatch_queue_create(), the global concurrent queues
schedule blocks as soon as threads become available ("non-FIFO" completion order). The global concurrent
queues represent three priority bands:
• DISPATCH_QUEUE_PRIORITY_HIGH
• DISPATCH_QUEUE_PRIORITY_DEFAULT
• DISPATCH_QUEUE_PRIORITY_LOW
Blocks submitted to the high priority global queue will be invoked before those submitted to the
default or low priority global queues. Blocks submitted to the low priority global queue will only be
invoked if no blocks are pending on the default or high priority queues.
So, they are queues which run on background threads as and when they become available. They're "non-FIFO" so ordering is not guaranteed.