Erbium acetylacetonate
Identifiers
3D model (JSmol)
  • InChI=1S/3C5H7O2.Er/c3*1-4(6)3-5(2)7;/h3*3H,1-2H3;/q3*-1;+3
    Key: FGQSJRDKBCVFHH-UHFFFAOYSA-N
  • CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.[Er+3]
Properties
C15H21ErO6
Molar mass 464.586 g·mol−1
Appearance pink crystals[1]
Melting point 103 °C (376 K)[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Erbium acetylacetonate is a coordination compound, with the chemical formula of Er(C5H7O2)3, or Er(acac)3 for short. It can be prepared by the reaction of metal erbium[2] or erbium trihydride[1] and acetylacetone. Erbium chloride could also react with ammonium acetylacetonate to obtain erbium acetylacetonate, which can be recrystallized in toluene.[3] Its anhydrous form is stable in dry atmosphere and forms a hydrate in humid air.[4] The anhydrous form cannot be obtained by heating the hydrate in humid atmosphere.[5] It begins to decompose at 190 °C, and erbium oxide can be obtained by continuous heating at 505 °C.[3]

References

  1. 1 2 3 Janice M. Koehler, William G. Bos (December 1967). "A novel synthesis of some anhydrous rare earth acetylacetonates". Inorganic and Nuclear Chemistry Letters. 3 (12): 545–548. doi:10.1016/0020-1650(67)80023-0. Retrieved 2021-09-20.
  2. ↑ J.R. Blackborow, C.R. Eady, E.A.Koerner Von Gustorf, A. Scrivanti, O. Wolfbeis (March 1976). "Chemical syntheses with metal atoms". Journal of Organometallic Chemistry. 108 (3): C32–C34. doi:10.1016/S0022-328X(00)92025-4. Archived from the original on 2018-06-26. Retrieved 2021-09-20.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  3. 1 2 J. Blanusa, B. Antic, A. Kremenovic, A.S. Nikolic, L. Mazzerolles, S. Mentus, V. Spasojevic (November 2007). "Particle size effect on Néel temperature in Er2O3 nanopowder synthesized by thermolysis of 2, 4-pentadione complex". Solid State Communications. 144 (7–8): 310–314. Bibcode:2007SSCom.144..310B. doi:10.1016/j.ssc.2007.09.003. Archived from the original on 2018-06-16. Retrieved 2021-09-20.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  4. ↑ Trembovetskii, G. V.; Martynenko, L. I.; Murav'eva, I. A.; Spitsyn (1984). "V. Synthesis and study of volatile rare earth acetylacetonates". Doklady Akademii Nauk SSSR (in Russian). 277 (6): 1411–1414. ISSN 0002-3264.
  5. ↑ Martynenko, L. I.; Murav'eva, I. A.; Khalmurzaev, N. K.; Spitsyn, V. I. Preparation of volatile rare earth element tris(acetylacetonates) by the heating of their hydrates. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1984. 6: 1207-1211. ISSN 0002-3353. language=ru
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