I'm just tring to generate next xml code by SimpleXMLElement() using :
<WebOrders xmlns="http://microsoft.com/wsdl/types/"
xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"
xmlns:xsd="http://www.w3.org/2001/XMLSchema">
But code like that
$webOrders = new SimpleXMLElement('<WebOrders/>');
$webOrders->addAttribute('xmlns', 'http://microsoft.com/wsdl/types/');
$webOrders->addAttribute('xmlns:xsi', 'http://www.w3.org/2001/XMLSchema-instance');
$webOrders->addAttribute('xmlns:xsd', 'http://www.w3.org/2001/XMLSchema');
makes
<WebOrders xsi="http://www.w3.org/2001/XMLSchema-instance" xsd="http://www.w3.org/2001/XMLSchema" xmlns="http://microsoft.com/wsdl/types/"><WebOrder/><WebOrder/></WebOrders>
only.