Rijndael is a block cipher that won the Advanced Encryption Standard competition. A subset of it was standardized as AES (FIPS 197) in October 2000.
Rijndael is a variable blocksize (only 128 bits standardized in AES), variable keysize (only 128,192 and 256 bits in AES) block cipher. The number of rounds is key-size dependent.
Rijndael is not widely supported, most cryptography libraries supporting only the AES subset. The exception being the .NET platform which supports more block sizes. Keep in mind that using a non AES compatible blocksize/keysize combination can lead to interoperability nightmare and that the security of Rijndael hasn't been widely studied outside of the AES subset.
https://learn.microsoft.com/en-us/archive/blogs/shawnfa/the-differences-between-rijndael-and-aes explains the difference between the AES standard, .NET implementation and the original Rijndael cipher.