The XYZ file format is a chemical file format. There is no formal standard and several variations exist, but a typical XYZ format specifies the molecule geometry by giving the number of atoms with Cartesian coordinates that will be read on the first line, a comment on the second, and the lines of atomic coordinates in the following lines.
The XYZ file format is a chemical file format. There is no formal standard and several variations exist. See the Wikipedia article on the XYZ file format for more information.